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The newer client has much less syncing issues too – if you’re not sure what one you’re using, check what executable is running. There’s no deployment of the app required then, so you won’t need to use or modify OneDrive for Business.
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You’ll need Windows 10 1709+ for this, as that’s the first version of Windows 10 that has OneDrive baked in. It’s just OneDrive now, even though the backend is OneDrive for Business as part of an Office 365 subscription. OneDrive for Business from the client’s perspective has been dropped. If you’re looking at starting to use OneDrive for Business and you’re working with a PCs joined to a local domain, you can now have a seamless sign in experience for end users (Note that the Group Policy setting for this is in preview according to the documentation).
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